The initial question was "with an assembled engine". That precludes pulling the head.
I have done it "in the car" by pulling and "cc-ing" the head and then "cc-ing" the block side with the piston at TDC. Of course, this only works with a dished or flat-top piston that sits below the deck. If you know the precise dimensions of the piston and where it sits in relation to the deck, you can calculate all of that and just "cc" the head. But we are talking about pulling the head.
I'd be real interested to know how the measurement device mentioned would work. Pretty hard to tell the remaining volume at TDC without injecting a fluid in.
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Mike Conatore
ITA 1989 240SX
Olympia, WA